El Conejo Brecker Aprende A Ser Cuidadoso (Brecker Bunny)

Hilary Bilbrey

Mechanism of base catalyzed transesterification of vegetable oil Figure shows the quantity of various raw materials to produce Kg of biodiesel. From this stage, product streams of a mixture of partially esterified oil, methanol and KOH; and a mixture of Glycerine and Soap result. From this stage, the glycerine and soap produced joins the stream from the first stage. The Methyl Ester product moves onto the washing stage.

This acts to remove any remaining soap, glycerine or catalyst that remains in the stream. The waste stream undergoes a process of demethanolisation and water removal to leave crude glycerine, and small quantities of triglycerides and catalyst. The methanol and water removed are separated and recycled into the transesterification and washing stages respectively.

The methanol and water are recycled, resulting in the product of purified Methyl Ester, Biodiesel. En la Figura 7. De nuevo, la cantidad de contenido de aceite crudo en la semilla depende de la calidad de la semilla. Por lo tanto, para garantizar la consistencia de los productos, es esencial disponer de materias primas consistentes. El metanol y el agua se reciclan, lo que da como resultado el producto: Also the gums and other impurities should be removed from the oil for better product yield and quality. Therefore, it is essential that oil should be pre-treated to meet above limit.

The pre-treatment of the oil is carried out in the preparatory section. Bleaching is carried out to lighten the colour of the oil. Following sections are used for production of biodiesel from the oil. Crude non-edible oil is the usual feed stock eg. The oils have impurities which interfere with the process of trans-esterification and must be removed before the process in a Preparatory step. Then soap stock formed due to chemical reaction is allowed to settle at the bottom of the neutralizer from where it is taken out into soap pan, as soap will complicate the separation process.

The free fatty acids are distilled out and condensed separately for further conversion to Methyl-ester. Bleaching Neutralized oil is drawn into the second vessel called bleacher where colour of oil is removed by bleaching process with aid of chemicals such as carbon black and bleaching earth.

Stirring is also continued. Bleaching process is done under vacuum. Bleached oil then goes to the filter press where bleaching earth and chemicals are separated. The refined oil if meeting the following standards shall be introduced to the transesterification section. Tranesterification Section The transesterification process flow chosen is similar to a cross flow. The feedstock and the intermediate product, respectively, flow successively through the two mixer-settler units, both units being supplied with methanol and catalyst in parallel. The reactors are of multi-stage design, comprising various reaction chambers in order to achieve maximum conversion efficiency to methyl ester.

The settlers allow phase separation to reach virtually the limit of solubility. This is of great benefit for the downstream processing of the phases rich in ester and glycerin. This process configuration is supported by a defined temperature profile adjusted along the mixer-settler arrangement. The ester-rich phase still contains methanol, glycerin, small amounts of catalyst, soaps and high boiling components. In order to remove the water-soluble substances, the ester phase is washed.

To avoid the formation of emulsions, any soap that may be present is previously split by adding acid. The washed ester still contains some water, being vacuum-dried in a dryer circuit to adjust the tolerable water content. The high-glycerin phase is collected in a pump tank together with the wash water because of its methanol and glycerin contents.

In this process, the catalyst decomposes into caustic soda solution and methanol in the presence of water. The catalyst in liquid form is added to the methanol by means of metering pumps. As the catalyst is sensitive to water, the catalyst pump tank may be protected with a nitrogen layer.

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Diluted hydrochloric acid is prepared automatically and can be added to the methyl ester to be washed. All gases vented off from the mixer-settlers, from the catalyst pump tank and the methanol pump tank are routed to a condenser where they are partly condensed and returned to the process in liquid form. The methanol containing phases e. By means of a pump, the dried methyl ester is continuously delivered to the methyl ester storage tank provided by customer.

The free fatty acids present in vegetable oils are eliminated in the preparatory section mentioned above. The high-free-fatty acid feedstock is mixed with alcohol and acid in a separate reactor, converting all free fatty acids into methyl esters. The evaporator system has two re-circulating evaporation circuits stages maintained under vacuum; each re-circulating evaporation circuit is composed of a heat exchanger and evaporator section.

The vapors from the last evaporator stage are precipitated in a condenser. The concentrated glycerol solution is transferred to a storage tank for storage and sale. This operation is only required if the project is intent on capturing this additional value at the expense of significantly higher capital and operating costs. Base catalyzed transesterification with refined oils 2.

Base catalyzed transesterification with low fatty acid greases and fats 3. Acid esterification followed by transesterification of low or high FFA free fatty acid fats and oils Many other processes are being developed, which include the following. Some companies offer pre-made turn-key plants, some will custom build a turn-key plant to suit specific customer needs, while others offer engineering services for a locally built, custom plant.

All options have advantages and disadvantages. Most of the high-tech biodiesel plant manufacturing companies offer plants that are economically feasible for centralized, large-scale production using a continuous process. In order to reach these economies of scale, these plants operate mostly on virgin oils. Decision Making Criteria and Parameters A variety of process options were investigated and evaluated with respect to the volumes and characteristics of feedstock, products and by-products, capital and operating costs, production flexibility, and the ability to meet required finished product specifications on a consistent and reliable basis.

This included an analysis of batch vs. The Company considered the following critical success factors prior to making the final choice for the technology platform: The selection of appropriate technology for production of bio-diesel requires careful selection of processing steps, catalysts, and downstream process integration. The quality of vegetable oils, particularly FFA and moisture content, plays an important role in identifying the technology suitable for a particular situation. To reduce the cost of bio-diesel production, value-addition options for by-products such as oil cake and glycerine are also being researched.

Important factors to be considered for selection of appropriate technology to produce bio-diesel include the following. The proposed Jatropha plantation shall be completed in and the first exploitable harvest shall be available in Therefore, following observations are very essential to be followed: With own Jatropha feed stock, the company shall start the production in first oil extraction and biodiesel plant of 10 tpd capacity in The plant either shall be run on reduced capacity utilization in since seed available for oil extraction shall not be sufficient to run for days in a year.

It is recommended that company may procure feedstock from the market to use both the plants on full capacity. After this the company feedstock shall be sufficient to run both the plants. Since the production of feed stock shall be increased every year it shall be appropriate to install two number of biodiesel plants in a phase manner of 5 tpd capacity.

Equipment order will be possible after negotiations with producers of different parts and completing installation plan. Quantity of agricultural tools needed was estimated for a farm with total arable area 1, ha. Site preparation includes mainly construction works: This will be done by subcontractor. We can start processing of oil right after site preparation, because this does not require complicated technology.

So, installation of oil processing equipment oil presses, filters, cisterns and offering oil processing services can be started at the beginning of the year. Experience in the rapidly growing biodiesel market in Europe shows that the legally demanded level of quality EN is often not achieved due to poor process technology and inadequate production management. As such the quality assurance for biodiesel is very essential since off specification biodiesel shall not only damage the engine parts but also shall be hard to be sold. Sulphated Ash ISO 0.

Specific Gravity The specific gravity is a relative measure of the density of a substance. The specific gravity of conventional No. Figure given below shows a hydrometer for measuring specific gravity. Other methods are also in common us Hydrometer for measuring specific gravity Kinematic Viscosity To define kinematic viscosity it is useful to begin with the definition of viscosity. We intuitively understand viscosity as evidenced by the fact that we know, for example, honey is more viscous than water. There is a hydrodynamic definition of viscosity as well.

Technically it is the ratio of the shear stress to the shear rate for a fluid. The test is usually conducted by measuring the time required for a volume of liquid to flow under gravity through a calibrated glass capillary tube. The kinematic viscosity is then equal to the product of this time and a calibration constant for the tube. Biodiesel is more viscous than No. Flash Point A key property determining the flammability of a fuel is the flash point. The flash point is the lowest temperature at which an applied ignition source will cause the vapors of a sample to ignite.

Therefore, it is a measure of the tendency of a sample to form flammable mixture with air. The flash point is determined by heating a sample of the fuel in a stirred container and passing a flame over the surface of the liquid. If the temperature is at or above the flash point, the vapor will ignite and an easily detectable flash can be observed. Figure below shows the test cup for the apparatus.

The cup is filled with fuel and heated with an external heater. The agitator ensures that the fuel temperature is uniform. A small open flame is maintained from an external supply. Periodically, the stirrer is stopped and the flame is pivoted down to an opening in the top of the cup to see if the fuel vapors will ignite. The ignition source is shown Figure below. When the flash point has been reached, there will be a small flash that is sometimes accompanied by an audible popping sound. Occasionally, the flash may actually extinguish the flame on the ignition source.

For a pure substance the boiling point is a single temperature value. However, for a mixture of hydrocarbons as exists in diesel fuel there is a range of boiling points for the different constituent chemical species. The distillation test is an alternative procedure for determining the volatility characteristics of a petroleum product the distillation characteristics, i.

Distillation limits are commonly included in petroleum product specifications due to the number of chemicals species that can be present. The standard procedure for measuring the boiling point range for diesel fuels is the distillation test, which is ASTM D The simple distillation apparatus used for this test is shown in Figure below. To run the test, a simple batch distillation process is conducted on a sample of the fuel and boiling point data are collected. Higher Cetane numbers indicate shorter times between the injection of the fuel and its ignition.

Higher numbers have been associated with reduced engine roughness and with lower starting temperatures for engines. The cetane number is an engine-based test. It is based on a special engine produced by the Waukesha Engine Company that is similar to the Octane Test Engine used for rating gasolines. The engine is a single cylinder, indirect injection diesel engine.

The combustion chamber is shown in Figure below. Then the engine is switched to operate on a blend of two reference fuels. Different blends are tested until a formulation is found that restores the ignition delay to 13 degrees. The primary reference fuels are n-cetane n-hexadecane , which has a cetane number of and heptamethylnonane HMN , which has a cetane number of When the ignition delay is restored to 13 degrees, the cetane number is computed from the following relationship.

Two ASTM methods are available for computing the cetane index.

ASTM standard D gives the following empirical equation for the cetane index: ASTM standard D gives the cetane index according to the following four-variable equation: The cloud point is the temperature at which a cloud of wax crystals first appears in a liquid upon cooling. Operating at temperatures below the cloud point for a diesel fuel can result in fuel filter clogging due to the wax crystals. The apparatus used for this test is shown in Figure below.

The cloud point is an important property for biodiesel since biodiesel fuels typically have higher cloud points, i. This feature has implications on the use of biodiesel in cold weather applications. A summary of the procedure steps is 1 the sample is cooled in a Peltier device at a constant rate, 2 the sample is continuously monitored by optical detectors, and 3 the temperature is recorded that corresponds to the first formation of a cloud in the fuel.

The repeatability of the cloud point test is less than0. The pour point is the lowest temperature at which a fuel sample will flow. The pour point also has implications for the handling of fuels during cold temperatures. Copper Strip Corrosion Detection of copper corrosion from petroleum products by the copper strip tarnish test measures the degree to which the fuel can have a corroding effect on various metals. The corrosivity of a fuel has implications on storage and use of the fuel. Then the strips are washed in a solvent and compared to the descriptions in Table given below.

Light orange, almost the same as freshly polished strip b. Dark orange 2 Moderate Tarnish a. Multicolored with lavender blue or silver, or both, overlaid on claret red d. Brassy or gold 3 Dark Tarnish a. Magenta overcast on brassy strip b. Multicolored with red and green showing peacock , but no gray 4 Corrosion a. Transparent black, dark gray or brown with peacock green barely showing b.

Graphite or lusterless black c. Glossy or jet black Ramsbottom Carbon Residue Ramsbottom Carbon Residue of Petroleum Products determines the amount of carbon residue left after evaporation and pyrolysis of an oil, indicating its relative propensity to form coke. It is a potential indicator of the likelihood that a fuel would form deposits from carbon in an engine's combustion chamber. Heating Value, Net and Gross There are actually two heating values in common use, the higher, or gross, heating value and the lower, or net, heating value.

Both quantities are measured using a calorimeter where the heat transfer from the hot gases resulting from combustion of the fuel with air is measured as the gases are cooled to the initial temperature of the reactants. The higher heating value assumes that all of the water in the products is condensed liquid while the lower heating value assumes all of the water is present as vapor, even though the product temperature may be below the dew point temperature.

The lower heating value is the most common value used for engine applications. It is used as an indicator of the energy content of the fuel. In general, the higher the heating value of the fuel, the less fuel that will be required to do a given amount of work. Acid Number Acid number is the quantity of base, expressed as milligrams KOH per gram of sample, required to titrate the sample to a specified end point Biodiesel limit 0. The acid number is also a measure of free fatty acids. The free fatty acids can lead to corrosion and are a symptom of water in the fuel or fuel oxidation.

This is also an indication of the condition of the stability of the fuel, because the acid number increases as the fuel ages. Test method - The sample is dissolved in a mixture of toluene and iso-propanol that contains a small amount of water. The sample is titrated potentiometrically with alcoholic potassium hydroxide. The meter readings are plotted against the respective volumes of titrating solution and the end points are taken at well defined inflections in the resulting curve. It is applicable to naphthas, distillates, oils, gasoline, diesel, and biodiesel and jet fuel.

Some process catalysts used in petroleum and chemical refining can be poisoned when trace amounts of sulfur are present. Sample combustion gases are next exposed to UV light. The SO2 is excited, from which fluorescence is emitted as it returns to its stable state. The fluorescence is detected by a photomultiplier tube and the resulting signal is a measure of the amount of sulfur contained in the sample.

Sulfated Ash This test method determines the amount of mineral ash remaining after a fuel is burned. For biodiesel, this test is an important indicator of the quantity of residual metals in the fuel that could come from the catalyst used in the esterification process. The lower limit of this test is 0.

Test Method — The sample is ignited and burned until only ash and carbon remain. The iodine value is an indicator of the unsaturation of the fuel, which has been linked with formation of engine deposits and problems in storing the fuel. Water and Sediment This test method covers the determination of the volume of free water and sediment in middle distillate fuels. This test is a measure of cleanliness of the fuel.

For B biodiesel it is particularly important because water can react with the esters to make free fatty acids and can support microbial growth in storage tanks.

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This method used to measure water and sediment is only sensitive to free water. It uses a centrifuge to separate small water droplets and particles to be sure they do not exceed 0. An earlier method D specified that a solvent should be added to allow the measurement to include dissolved water but since diesel fuel will only dissolve about 50 ppm of water, this has little impact on whether the fuel exceeds the specification value.

This test is particularly important when working with biodiesel because biodiesel is usually water-washed to remove traces of soap and free glycerol. Vacuum drying is usually needed to remove residual water following the washing process. Test Method - A ml sample of undiluted fuel is centrifuged in a tube readable to 0.

After centrifugation, the volume of water and sediment which has settled into the tip of the centrifuge tube is read to the nearest 0. Lubricity Lubricity can be defined as: The lower the friction the higher the lubricity. Pure biodiesel and high level blends have excellent lubricity. Gas Chromatography Chromatographic methods are used to separate a mixture of compounds based on their physical properties. It determines the amount of glycerol in derivatized form , mono- and diacylglycerols both also in derivatized form , triacylglycerols, and methyl esters in a biodiesel sample.

In GC, the mixture is separated mainly by the boiling point and the structure imparting a feature termed polarity of the individual compounds. To carry out a GC analysis, the sample is usually dissolved in low concentrations in an organic solvent and then injected into the gas chromatograph. In some cases, a sample needs to be derivatized with a specific reagent in order to obtain a useful gas chromatogram. This is the case for biodiesel. Glycerol and the mono- and di-acylglycerols contain free hydroxyl groups, causing these materials not to perform well in GC.

Derivatization in the case of biodiesel with a silylating reagent improves their performance considerably. Derivatization can provide better resolution between compounds with similar properties. After injection into the gas chromatograph, the sample is separated on a column. A column is a long, thin path capillary tube that contains a material with which the sample components interact more or less strongly depending on their structure polarity! Usually, the solvent used and, if applicable, residual derivatizing agent used for preparing the sample are the first materials to elute i.

When the detector detects a material eluting from the column at a certain retention time i. Generally, the integrated value of the peak an amplitude over time is proportional to the amount of material causing them. This constitutes the usefulness of GC in quantifying the amounts of components in a mixture Fuel Stability A fuel is considered unstable when it undergoes chemical changes that produce undesirable consequences such as deposits, acidity, or a bad smell.

There are three different types of stability commonly described in the technical literature. Thermal stability addresses fuel changes that occur due to elevated temperature. These changes may occur at conditions encountered in modern fuel injection systems as fuel is recirculated through the engine cylinder head and back to the fuel tank. Oxidative stability refers to the tendency of fuels to react with oxygen at temperatures near ambient.

These reactions are much slower than those that would occur at combustion temperatures, and they produce varnish deposits and sediments. Storage stability is also a frequently used term and refers to the stability of the fuel while it is in long-term storage. These terms are not necessarily exclusive terms. For example, oxidative attack is probably one of the primary concerns of storage stability but storage stability might also involve issues of water contamination and microbial growth. El aceite crudo no comestible es la materia prima habitual, p.

Materia insaponificable, aquella que no se puede saponificar. La fase alta en glicerina se recolecta en un tanque de la bomba junto con el agua del lavado debido a su contenido de metanol y glicerina. El metanol que contiene fases p. Todas las opciones tienen ventajas y desventajas. Por lo tanto, es sumamente esencial que se sigan las siguientes observaciones: Cenizas sulfatadas ISO 0.

Por lo tanto, es una medida de la tendencia de una muestra para formar con el aire una mezcla inflamable. La siguiente figura muestra el recipiente de prueba para el aparato. El recipiente se llena con combustible y se calienta con un calentador externo. El agitador garantiza que la temperatura del combustible sea uniforme. Entonces se hace un cambio para que el motor funcione con una mezcla de dos combustibles de referencia.

El aparato usado para esta prueba se muestra en la siguiente figura. El resumen de los pasos del procedimiento es: La corrosividad de un combustible tiene implicaciones en el almacenamiento y uso del combustible. Color bronce u oro. Magenta nublado en la tira bronceada. Multicolor mostrando rojo y verde como pavo real , pero no gris. Grafito o negro sin brillo. Negro brillante o negro azabache. Esta prueba es una medida de la limpieza del combustible. Lubricidad La lubricidad se puede definir como: Generalmente, el valor integrado del pico y la amplitud en el tiempo, es proporcional a la cantidad del material que los causa.

The biodiesel industry has expanded far beyond a niche market to become a significant industrial player. Biofuels are taking on renewed global importance as countries seek to substitute the soaring price of conventional oil and cut hazardous emissions. Global output of biodiesel is between and million gallons annually.

Although Biodiesel can be marketed as an ordinary fuel and our calculations in Financial Planning section are based on market price of conventional diesel, we believe, that most perspective customers are farms, in-city transport companies and those who need lowest possible pollution levels in technological processes: Although with some limitations, this was true for years and seems to be accelerating due to political and economical reasons.

It is necessary to assume, however that because of future increasing of Biodiesel production over the world, prices of Biodiesel can go up only to a sustainable extent. We are part of rapidly growing biofuel business, which includes also producers of heating oils and oleochems. Unless sells of petrodiesel remain subject to excise and other taxes, our product would be uncompetitive on market. Biggest problem may appear if state imposes the above-mentioned taxes for Biodiesel, which however, is highly unlikely, because of strategic importance of alternative fuels for country.

Strategy and implementation summary Our company believes that qualitative approach will substantially expand the available market for us by creating a new supply route into the mainstream fuels infrastructure that does not exist today: Emphasize inherent qualities of Biodiesel and focus on target markets. We need to establish our business offering as a clear and viable alternative for our target markets. Strategy pyramid For placing emphasis on quality, our main tactics are technology expertise and developing our own supply network.

Our specific programs for technology are continuos learning and research. Specific programs for supply include cultivation of Jatropha seed and cooperative agreements with local farms. This shall be achieved by cost effective scientific farming of Jatropha with proper management. Value proposition We think our value proposition is quite clear and quite easily distinguished from most others in the market.

We offer ecology-friendly and renewable type of fuel at a reasonable market price.

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Competitive edge Our most important competitive edge is entering Jatropha cultivation and fuel supply industry with newest technologies and gaining experience and market share before competitors came. Unlike mineral fuel, Biodiesel is renewable energy source, with competitive cost and performance. Promotion We depend on direct contacts as our main way to reach new buyers. As we grow, however, we need to change the way we promote ourselves: We'll be developing our core positioning message: We will be using local newspaper advertising, radio, and cable TV to launch the initial campaign.

Distribution We focus on the market need for environment friendly fuel distributed through the authorized gas filling stations. We will also maintain close relationships with transport companies and agricultural enterprises. Sales strategy Our major intention is to keep levels of monthly production, sales, and collections close one to another. Because Biodiesel is highly liquid product, this goal can be implemented with right choice of distributors and suppliers m. Direct —cost of Biodiesel production is projected under Table: Biodiesel, glycerol and Jatropha cake We must charge appropriately for this unique type of feed stock, but we want also to predict revenues as close as possible and to eliminate market risk, so we plan to it as below Table: Sales programs There are three sales programs in this business plan: Biodiesel is planned to sell using direct mail, seminars, promotion programs and advertising in business newspapers.

Because Biodiesel is a valuable fuel for in-city transportation companies, direct mail to these and other companies would be effective tool in promotion. Ecology, energy, technology related seminars are effective in finding regional representatives, partners, suppliers and buyers of our product. Total budget for all these programs is shown in Profit and Loss Statement, Advertising and Miscellaneous expenses. The seed cake is an excellent fertilizer and has a waste market Glycerin be marketed to costematic, soap industries. Milestones The following table lists 1-st year milestones, with dates and budgets for each.

The milestone schedule indicates our emphasis on planning for implementation. The most important programs are Jatropha cultivation Stages 1 to Harvesting and equipment installation. We omitted secondary actions like office preparation, stationery purchase or calls to perspective customers. Management Our management philosophy is based on responsibility, mutual respect and entrepreneurial creativity. Our main management divisions are farming, processing, and sales. Farming handles cultivation of Jatropha; processing- pressing of oil seeds and production of Biodiesel.

We believe we have a good team for covering the main points of the business plan: Personnel plan The Personnel Plan reflects the need to bolster our capabilities to match positioning in the fuel and agricultural market. The need for labor force was estimated accordingly to industry experience and technological needs.

Project Financing Summary of finance required presented on the table below. We expect outside investor to finance the entire project and we offer him Direct costs were calculated in accordance to market prices of chemicals, all other expenses were also properly allocated in the income statement 6.

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This assumption and other financial indicators shown in the table below 8. There are three stages - plantation, extraction, and transesterification - are considered. These stages are considered to be separate entities in this calculation. Cost calculated for the seed is loaded to the extraction stage, assuming that the seed is bought by an extraction unit, and then the corresponding raw oil cost is calculated. Finally, the raw oil cost is loaded to the transesterification stage, again assuming that a transesterification unit is using this raw oil and transesterifying it to bio-diesel.

Unforeseen factors and developments our ability to implement its business strategy may be adversely affected by factors that the we Cannot currently foresee, such as unanticipated costs and expenses, interruptions to or delays in production, reduced demand for the Our product, technological change, loss of political support for Biodiesel or severe economic downturn. All of these factors may necessitate changes to the business strategy described in this document. Competition There can be no assurance those potential competitors of the company, which may have greater financial, research and development, sales and marketing and personnel resources than ours.

It is anticipated that the market will become increasingly competitive over the coming decade. Additionally, several other biofuels and renewable fuels could be introduced to the market as alternatives to mineral diesel. Should these alternatives be selected in the market the demand for Biodiesel could be diluted. Dependence on key personnel We believe that its future success will greatly depend upon the expertise and continued services of certain key executives and technical personnel, including the executive Directors We cannot guarantee the retention of such key executives and technical personnel.

As a result, our business, its results of operations and financial condition may be adversely affected. General risks Our business may be affected by the general risks associated with all companies in the energy industry. The prices received for our goods and products depend on numerous factors, many of which are beyond its control and the exact effect of which cannot be accurately predicted. Such factors include general economic and political activities, including the extent of governmental regulation and taxation.

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An investment could be affected adversely by changes in economic, political, administrative, taxation or other regulatory factors The company faces a number of industrial risks such as a dispute with its workforce and dependence on key suppliers, both of which may lead to a deterioration in financial performance. Risks associated with international sales. Operational risks The financial performance of the Company is at all times subject to operational risks. For example, the technology could face unforeseen refining problems, in which case production and financial performance would be delayed.

Unanticipated additional maintenance of the machine would also impact the production capacity and revenue projections. Storage tanks should be fully sealed at all times in order to ensure quality Biodiesel and to minimize moisture being added to the fuel. The risk of contamination of the pure vegetable oil or Biodiesel exists from transportation, expelling, storage and refining should the proper quality procedures and handling guidelines not be adhered. The Company is also at risk of the contamination of its raw materials supplies at source which may lead to stock write downs and an inability to supply customers.

The Company attempts to safeguard against this risk by checking materials prior to purchase and dispatch and on receipt at the relevant processing facility. Agricultural risk Our business may be affected by all general risks associated with agricultural production. Theft is also a concern in certain regions, should trees be deemed valuable as another commodity in those regions. The use of petro-diesel in engines creates a significant amount of greenhouse gas emissions that can be greatly reduced by substituting a blend of Bio diesel and petro-diesel or using percent Bio diesel.

Greenhouse gas emissions can be reduced in a number of ways through the Bio diesel production process including: The Bio diesel production process. Carbon sequestration, seed cake and Bio diesel are potential CER sources while glycerine is a potential additional revenue source. Bio diesel can be produced from plants such as rapeseed, palm, coconut, or soybean or from used cooking oil from restaurants.

Regarding Clean Development Mechanism projects, there is a great potential in the use of Jatropha Curcas, or Pine nut. Jatropha is a small tree that has the ability to grow in poor soils and tolerate low rainfall and droughts, as well as areas with high rainfall; it can often grow in areas where other plants cannot.

The study concluded that Bio diesel yields 3. In relation to carbon credits, it has been estimated that 1 hectare of Jatropha Curcas could result in CO2 emissions reductions of 10 tonnes per year Francis and Becker There is a large potential for CDM Bio diesel projects in many countries.

Other countries deemed to have potential for the establishment of Jatropha plantations include Indonesia, Namibia, Morocco and Paraguay. Research is being conducted throughout the world, funded by both developed and developing countries, on establishing plantations for Bio diesel and on producing Bio diesel. However, lack of experience in producing Bio diesel and problems with seed and oil storage causes risk of investment to be fairly high. Carbon credits can help to reduce this risk and encourage investment in Bio diesel. Including revenue from carbon credits from petro-diesel substitution and possibly carbon sequestration and nitrogen based fertilizer substitution; Bio diesel projects become considerably financially attractive.

Interest in the use of the seeds of Jatropha Curcas, as well as other plants, to make the oil is rapidly expanding. CDM potential is present in a large number of countries due to the number of types of plants from which Bio diesel can be made.

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The time for realizing the potential of Bio diesel in the carbon market has arrived. Necesitamos establecer nuestra oferta de negocio como una alternativa clara y viable para nuestros mercados objetivo. Nuestra estrategia se enfoca en el bajo costo del producto. Sin embargo, a medida que vayamos creciendo tendremos que cambiar la forma en que nos promovemos: Vamos a desarrollar nuestro mensaje central de posicionamiento para diferenciar nuestro producto de la competencia. La pasta de semillas es un excelente fertilizante y tiene un mercado de residuos.

Creemos tener un buen equipo para cubrir los puntos principales del plan de negocios: Financiamiento del proyecto En la siguiente tabla se presenta un resumen del financiamiento requerido. Se presentan otras suposiciones financieras en la siguiente tabla: Todos estos factores pueden necesitar cambios en la estrategia de negocios descrita en este documento. Unfortunately, there is no unified explanation on how to understand it.

At the same time, Supreme Audit Institutions SAIs worldwide have little or no experience in audits concerning sustainable energy. Thus, the aim of the Guidance is to help SAIs to understand issues concerning this topic and to identify a suitable audit approach.

The Guidance enables a reader: The Guidance respects the following four steps1: STEP 1 Understand the sustainable energy issue and its influence on society, economy, and the environment Step 1 aims to identify problematic issues regarding the sustainable energy in the respective country and their impact on society, economy, and the environment. Chapter 1 focuses on Step 1 and gives the reader a basic overview of the most used energy resources and their advantages and drawbacks, as well as of energy consumption, savings, and efficiency.

Chapter 2 focuses on this topic. STEP 3 How to choose audit topics Based on information obtained in Steps 1 and 2, auditors will identify areas that can be subject to an audit in the framework of legislative competencies and specify instruments appropriate for an audit or that are advisable to audit. Chapter 3 focuses on this issue and shows some approaches to potential topics on sustainable energy. It also contains an analysis of possible risks risk assessment. STEP 4 Design the audit Step 4 introduced in Chapter 4 explains audit planning and preparation of an audit on sustainable energy.

An audit logic matrix for performance audit of the sustainable energy issue also forms a part of Step 4. A logical follow-up of Step 4 is carrying out an audit which is discussed in Chapter 5. The Annexes provide practical tips, case studies of sustainable energy audits, tips for setting audit criteria from international and national legislation, a guide on how to carry out audits on grants, and a guide on how to cope with the issue analysis.

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  6. Sherlock Holmes and the Adventure of the Musgrave Ritual (Annotated)?
  7. The History of Don Quixote, Volume 1, Part 08.

All this information is completed by a general overview on the questionnaire survey we made and an overview on audits carried out in this field up to now. How to develop a Guidance Material in Environmental Auditing, available at www. We understand sustainable energy as an issue covering two main fields; the first one is energy generation from renewable energy resources RERs , and the second one is the most effective and economic use of renewable and non-renewable energy resources.

However, there are a number of obstacles that can hinder progress towards a broader use of sustainable energy, including: Each country should adopt measures to increase the proportion of energy produced from RERs in their energy mix. The broader use of RERs can make it possible to: Public funding may be used to promote and expand the sustainable energy field, through direct funding of projects realized and through research and technology development.

Thus, it is necessary to review and audit both the management of spending from public funds and the effectiveness of policies and programmes in achieving their stated objectives. The guide does not cover the transport and transport related policy tools. The transport issues are mentioned only marginally in the parts of the guide where it is appropriate for its logical structure.

Basic information on energy issues Biomass as a RER has a lot of advantages. For instance, biomass combustion does not increase the level of CO2 emissions in the atmosphere but it is necessary to replace e. Another advantage of biomass is that its combustion can be used e. Using biomass as a RER also has two potential disadvantages. Growing biomass crops may displace agricultural land that could be used for growing crops for food; more land is used for growing energy crops, deforestation and soil erosion occurs, and the foodstuffs market is affected.

Also, combustion of some biofuels can release a high amount of air pollutants into the atmosphere. Hydropower The energy of water can be obtained by using its flow kinetic power or its pressure pressure potential head , or also as a combination of both of these at the same time, which is typical for dam hydroelectric power stations.

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In general public-sector auditing can be described as a systematic process of objectively obtaining and evaluating evidence to determine whether information or actual conditions conform to established criteria. The capital cost of the transesterification plant depends on its capacity. Biodiesel is a new industry, but it is rapidly becoming an integral part of the global renewable energy scenario. Mexico, the native home of Jatropha plants, stands to benefit if such a Biofuel industry take off. Jatropha can grow on a wide range of land types, including marginal and waste land. It is one that pressingly needs to become a reality now. The yield of the seed per hectare area of production is a very significant factor in determining the final price of biodiesel.

Potential energy originates as a consequence of gravity and depends on a difference in elevation levels. It is also possible to use water heat gradient for energy generation. Currently, small hydroelectric power stations are being built, largely in place of former watermills and existing dams on smaller water courses.

Very simple, and therefore also economically acceptable, microturbine technologies are used when building such small hydroelectric power stations. Tidal energy uses the regularity of tides to generate energy by placing turbines in the direction of an incoming high tide stream or by periodically filling up and draining coastal basins or lagoons. Wave energy can be transformed into electricity in various mechanical or pneumatic ways. In most cases, these are still in the experimental stage. It is ideal to install the systems in places where a sea is metres deep, as this is where the wave energy is most efficient.

In tropical oceans, the thermal gradient between the water surface and water at a depth of 1 km can be used for obtaining energy so called OTEC technology - Ocean thermal energy conversion. The advantage of water energy is, in practice, its inexhaustibility and minimal environmental pollution. Hydroelectric power stations demand minimal servicing and maintenance and they can be operated from a distance. They can be put into operation during several tens of seconds and therefore can be used for covering immediate energy production demands, in particular in energy peak times it means in time when demand for electricity is increased , and also they can serve as a stand-by power supplies in cases of accidents.

Pumped-storage hydroelectric power stations can be also used for compensating energy drops that are caused by wind or solar power plants. Even though water energy ranks among the most widely used RERs, it also has some drawbacks. Hydroelectric power stations are characterized by high investment costs, particularly in the case of large hydroelectric power stations, and this goes hand in hand with impacts on the environment such as needing to flood large areas, destroying water systems, decline of biodiversity and possible social effects.

The amount of energy generated also can depend on seasonal water flow rate fluctuations e. Tidal power stations also suffer from another disadvantage: Also, the sites wellsuited for the construction of these power stations are often remote from points where energy is used. While the potential to use the energy of sea waves is great, a negative aspect is that wave generation depends on the force of wind. Rotors of turbines driven by streaming air can be used to generate energy.

The size of the turbines varies anywhere from small simple turbines fitted onto the roofs of family houses up to individual large turbines with an output power of over 2MW that can be grouped at wind farms built both on land or at sea. Wind energy is easy to convert to electric power and does not generate emissions or waste. Electric power from large installations is fed directly to the grid, while small units e. The main problems with wind turbines are high investment costs and construction being limited to areas with adequate average wind speed.

Reservations have also been voiced about the noise generated by the turbines and their domination in the countryside, which can be disturbing. Because energy generated by wind power is intermittent, other energy e. Bodypack transmitter General description: Combining the bodypack transmitter with an headworn or clip-on microphone, will give you total freedom of movement during your tour.

You will have both hands free to describe an object, make a presentation and express your point. The transmitter can be easily and comfortably operated, and is highly robust. The back-lit display confirms channel choice, the radio signal and the status of the battery. Two jacks for the microphone and line ensure variable utilization. For example, you will be able to transmit an external audio source such as music from a portable CD player via your transmitter and continue to talk or mute the microphone.

Product name, Article No. ME 2-N - Clip-on mic omni-directional Clip-on mic omni-directional; 3. ME 4-N - Clip-on mic cardioid Clip-on mic cardioid; 3. It fulfils the most stringent demands on sound quality and is extremely rugged. A special Umbrella diaphragm and a welded housing protect the MKE 2-ew Gold against sweat and moisture, making it an ideal choice for theatrical productions.

HS 2 ew - Headmic omni-directional Headmic omni-directional; 3. ME 3-N - Headmic super cardioid Headmic super cardioid; 3. It features a rugged metal body, high suppression of handling noise and excellent rejection of feedback and spillage. Rugged, durable construction, insensitive to handling noise.

The e efficiently suppresses sounds emanating from outside its pick-up angle, and is fitted with a hum compensating coil for reducing electromagnetic interference. CL 1 - Cable Cable for audio devices 3. CL 2 - Mic cable Mic cable 3. CL 1 - Cable Cable para dispositivos de audio, jack de 3. Designed and constructed to the same electronics and audio quality standards as Sennheiser's award-winning. RF wireless systems, our infrared systems offer efficient, dependable commu-nications for a large variety of applications.

From portable small-area systems for single- or two-channel use to complex, large-area systems for multi-channel use, we can provide an infrared system for nearly any need. Our Series high sub-carrier frequency system, for instance, has been designed to eliminate the interference problem that plagues other systems to provide clear, uninterrupted audio. Sennheise's Digital Conference Systems are designed to work dependably and simply in any con-ference setting. The individual delegate units can be combined in a variety of configurations to give maximum flexibility and ease of use, and all conference systems can be easily interfaced with both infrared and interpretation systems for complete conference solutions.

The Televic TIS Series interpretation systems perfectly complement our conference and infrared systems by offering a variety of translation system options. Offering simultaneous language trans-lation capabilities of up to eight different languages, these systems provide unparalleled operation in international conference settings.

Sennheiser's GuidePORT personal tour system provides a high-quality interactive experience for visitors of museums, theme parks, aquariums, art galleries and more. Users simply approach an exhibit, and the audio program is triggered. Employing Sennheiser's world-renown RF wireless technology, Tourguide systems offer the utmost ease and comfort for any guided tour situation.

Not only are their easy-to-use components durable and great-sounding, but they offer a cost-effective solution to traditional guided tours. Sennheiser's DirectEar Soundfield Amplification System solves this problem by providing mild amplification designed to optimize speech intelligibility. Now everyone can hear equally regardless of where they are seated in the classroom. All Sennheiser Information Systems can be combined with additional Sennheiser, Innovason, TurboSound, and Chevin products and components to add functionality and versatility.

In addition to the products offered in this brochure, Sennheiser has a full line of audio products which may complement your system. Please contact us at , or at http: Its single- or dual-channel operation 2. RI S Single-channel body pack receiver with neck cord and 3. HDI Two-channel stethophone receiver with squelch. With available mounting hardware, the SI 20 can be easily mounted on walls or ceilings. SZI30 This compact, small to medium-area emitter panel perfectly complements the SI 20 modulator in situations where full, large-area coverage is unnecessary.

This easy-to-use, integrated system offers a cost-effective solution for ADA compliance for the hard of hearing, simultaneous language interpretation, and other assistive listening applications. Please use SI 30 or SI With its new SDC conference system, Sennheiser brings the benefits of digital communication technology to the conference room: Optional software allows the conference management to be handled directly from a PC. SDC can be coupled with a Televic System, allowing for simultaneous language interpretation. SDC is a new generation of mobile, readily expandable equipment essential for modern communications for conferences of all types and sizes.

The Delegate Unit and Its Functions The delegate unit features a built-in loudspeaker, allowing the participant to directly hear all audio information, e. The unit's electret microphone ensures that every word is transmitted clearly to all participants. The mic is fitted with a red LED ring which serves as an indicator of who is allowed to take the floor, who has "applied" for a comment, etc.

Controlling Functions for the Conference Chairperson A simple change in configuration is all that is needed to turn the delegate unit into a chairperson unit. Two control keys which are otherwise inactive will be assigned special functions, enabling the chairperson to control the meeting. For example, he or she can determine who is allowed take the floor, and can pass on the "speaking rights" in queue sequence.

For large conferences up to four chairperson units may be configured. Up to 25 conference consoles can be hooked up to the central unit - that's all there is to setting up a basic conference system! Beyond 25 consoles, add a power supply. Using the central unit, a delegate unit can be programmed as a chairperson unit. During the conference, the central unit "opens" and "closes" the speaking channels. Three basic conference modes can be chosen on the central unit. In "Request" mode, the chairperson allows speaking rights by pressing the "next" key.

He continued touring during , and live appearances from this period were featured on the Party in Session -- Live album, released later that year. Rose's large international following was treated to another world tour, and thus it wasn't until that his next album, Bonanza, appeared. The record created a new controversy by its inclusion of love songs.

The singer has continued touring and recording, and in his Never Give It Up album was released. An American tour followed in the new year. Michael Rose View on Apple Music. Oct 23, Skydive - Single 1 song. Top Songs See All. A Day In the Life feat. Michael Rose and Menny More. Easy Star All-Stars African Queen - Single Shine Eye Gal feat. The Best of Michael Rose Party in Session - Micheal Rose Give Back the Night.

English to Spanish translator 35+ years of experience, any field.

Sound Box Essentials Platinum Edition. Peace and Love In the Ghetto - Single. African Queen - Single. Thanks for Nothing - Single. Live Albums See All. Live San Francisco 2b1 Maritime Hall. The Best of Michael Rose. Party in Session - Micheal Rose Live. Appears On See All. Illegal The Remixes [feat. The Birth of an Opera: Fifteen Masterpieces from Poppea to Wozzeck.

Brecker Bunny Learns to Be Careful. El conejo brecker aprende a ser cuidadoso. Brecker Bunny Asks for Help.